^ In reality, no one will remember what you wore on the first day of school (as long as you're not wearing anything dirty/ripped/too flashy, etc.)
Also, in large classes, I guarantee you that even if you were to go talk to your profs and "mingle" on your first day, they won't remember or care, really.
Getting to know your prof should be done through asking thought-provoking questions, and coming up with ideas no one else in the class can think of, rather than simply talking to them just so you can make a sound.
Last but not least, don't be nervous. Be excited!
First week of classes is when you'll discover the campus and get a little taste of university life.
Enjoy it! Before you know it, you'll be drowning in assignments/essays/quizzes.
Good luck!